Translation-invariant bipolaron theory of heat capacity of layered high-temperature superconductors
Abstract:
In this paper, the thermodynamics of a two-dimensional charged Bose gas with a gap excitation spectrum of translation-invariant bipolarons is considered. Analytical expressions are obtained for the Bose condensation temperature Tc, the chemical potential μ(T), the internal energy U(T), the heat capacity CV(T), and the magnitude of the heat capacity jump ΔCV at the critical point. A quantitative agreement between the model and the classical calorimetric data of Loram et al. (1994) is carried out for the optimally doped high-temperature superconductor YBa2Cu3O6.92 (Tñ ≈ 91.5). It is shown that the regime of a strong energy gap (w0 ≫ Tñ, w0 -optical phonon frequency) allows one to describe with good accuracy the macroscopic λ-peak of the electron heat capacity with the participation of only a small concentration of TI bipolarons from the total concentration of the carrier density in the CuO2 planes.